When does Pearl enter Valorant's Competitive queue?

Pearl is the latest map in Valorant and will be available in the Competitive queue tomorrow. It went live with Patch 5.0 on June 22, with the launch of the new Episode.

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A professional VALORANT analyst's guide to playing Pearl - Upcomer

Beginner's Guide to Valorant - Valorant Guide - IGN

Valorant Update 5.0 Patch Notes

Valorant update 5.0 patch notes add Pearl map and Ascendant rank

Patch Notes/6.0, Valorant Wiki

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Valorant Episode 5 - New Map Pearl, Competitive Rank, And More - GameSpot

Sea is calling! Are you ready to dive in?: Valorant Twitter teases the addition of Pearl in Competitive queue - The SportsRush

A professional VALORANT analyst's guide to playing Pearl - Upcomer

Patch Notes 3.10: Chamber release and competitive queue updates, VALORANT Esports News